Benzodithiophene Homopolymers Synthesized by Grignard Metathesis (GRIM) and Stille Coupling Polymerizations

dc.contributor.ISNI0000 0003 8371 1336 (Gnade, BE)
dc.contributor.LCNA00049719‏ (Gnade, BE)
dc.contributor.VIAF55039821 (Stefan, MC)
dc.contributor.authorMagurudeniya, Harsha D.en_US
dc.contributor.authorKularatne, Ruvini S.en_US
dc.contributor.authorRainbolt, Elizabeth A.en_US
dc.contributor.authorBhatt, Mahesh P.en_US
dc.contributor.authorMurphy, John W.en_US
dc.contributor.authorSheina, Elena E.en_US
dc.contributor.authorGnade, Bruce E.en_US
dc.contributor.authorBiewer, Michael C.en_US
dc.contributor.authorStefan, Mihaela C.en_US
dc.contributor.utdAuthorGnade, Bruce E.en_US
dc.contributor.utdAuthorBiewer, Michael C.en_US
dc.contributor.utdAuthorStefan, Mihaela C.en_US
dc.date.accessioned2014-10-07T20:45:45Z
dc.date.available2014-10-07T20:45:45Z
dc.date.created2014-04-16
dc.date.issued2014-04-16en_US
dc.description.abstractPoly{4,8-bis(95-dodecylthiophene-2-yl) benzo[1,2-b: 4,5-b'] dithiophene} has been synthesized by both Grignard metathesis (P1) and Stille coupling polymerizations (P2). Polymers P1 and P2 were characterized and their optoelectronic properties, charge carrier mobilities, and photovoltaic properties were compared. The field-effect mobilities of the polymers were measured on both untreated and heptadecafluoro-1,1,2,2-tetrahydro-decyl-1-trimethoxysilane (FS) treated organic field effect transistor (OFET) devices. The polymers were also evaluated in bulk heterojunction (BHJ) solar cells with [6,6]-phenyl-C-71-butyric acid methyl ester (PC71BM) as the acceptor.en_US
dc.identifier.bibliographicCitationMagurudeniya, Harsha D., Ruvini S. Kularatne, Elizabeth A. Rainbolt, Mahesh P. Bhatt, et al. 2014. "Benzodithiophene homopolymers synthesized by Grignard metathesis (GRIM) and Stille coupling polymerizations." Journal of Materials Chemistry A 2(23): 8773-8781.en_US
dc.identifier.issn2050-7488en_US
dc.identifier.issue23en_US
dc.identifier.startpage8773en_US
dc.identifier.urihttp://hdl.handle.net/10735.1/4096
dc.identifier.volume2en_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.urihttp://dx.doi.org/10.1039/c4ta01739k
dc.rights©2014 The Royal Society of Chemistry. This article may not be further made available or distributed.en_US
dc.sourceJournal of Materials Chemistry A
dc.subjectPolymersen_US
dc.subjectPolymerizationen_US
dc.subjectGrignard Metathesisen_US
dc.subjectStille Couplingen_US
dc.subjectBenzodithiopheneen_US
dc.titleBenzodithiophene Homopolymers Synthesized by Grignard Metathesis (GRIM) and Stille Coupling Polymerizationsen_US
dc.typeTexten_US
dc.type.genrearticleen_US

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